As companies are fighting the battle of customer acquisition via both their online and off-line channels, they have invested heavily on their Web sites to retain the attention of Web surfers who just visit their company Web site, and transform them into potential customers who would purchase either from their Web site or from their physical store (Hoffman & Novak, 2000). Though marketers are aware that online marketing strategies are crucial to attract visitors to Web sites and make the Web site sticky (Hoffman et al., 1995; Morr, 1997; Schwartz, 1996; Tchong, 1998), little is known about the factors that can bring out such a compelling online experience. This chapter examines how specific Web atmospheric features such as dynamic navigation design, together with Web users’ surfing goals, can lead to an optimal online experience. In addition, the chapter also examines the consequences of an optimal surfing experience on consumers’ attitudes toward commercial Web sites/brands (promoted on these sites) and purchase intentions.