Graphene Based-Biosensor: Graphene Based Electrolyte Gated Graphene Field Effect Transistor

Graphene Based-Biosensor: Graphene Based Electrolyte Gated Graphene Field Effect Transistor

Mohammad Javad Kiani (Islamic Azad University, Iran), M. H. Shahrokh Abadi (Hakim Sabzevari University, Iran), Meisam Rahmani (Universiti Teknologi Malaysia, Malaysia), Mohammad Taghi Ahmadi (Urmia University, Iran), F. K. Che Harun (Universiti Teknologi Malaysia, Malaysia) and Karamollah Bagherifard (Islamic Azad University, Iran)
DOI: 10.4018/978-1-5225-0736-9.ch011
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Abstract

Because of unique electrical properties of graphene, it has been employed in many applications, such as batteries, energy storage devices and biosensors. In this chapter modelling of bilayer graphene nanoribbon (BGNR) sensor is in our focus. Based on the presented model BGNR quantum capacitance variation effect by the prostate specific antigen (PSA) injected electrons into the FET channel as a sensing mechanism is considered. Also carrier movement in BGNR as another modelling parameter is suggested. PSA adsorption and local pH value of injecting carriers on the surface of player BGNR is modelled. Carrier concentration as a function of control parameters (f, p) is predicted. Furthermore, changes in charged lipid membrane properties can be electrically detected by graphene based electrolyte gated Graphene Field Effect Transistor (GFET). In this chapter, monolayer graphene-based GFET with a focus on conductance variation occurred by membrane electric charges and thickness is studied. Monolayer graphene conductance as an electrical detection platform which is tuned by neutral, negative and positive electric charged membrane together with membrane thickness is suggested. Electric charge and thickness of the lipid bilayer (QLP and LLP) as a function of carrier density are proposed and the control parameters are defined. Finally, the proposed analytical model is compared with experimental data which indicates good overall agreement.
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Introduction

Background of Graphene Based-Biosensor

Graphene is a monolayer of sp2 bonded carbon atom, this sp2 bond makes the graphene structure apparently looks like honeycomb crystal as shown in Figure 1. Graphene is called the mother of graphite (many layers of graphene), because it can act as basic building block of these allotropes(Enoki, Kobayashi, & Fukui, 2007). Graphene is theoretically discovered back in the 1940s, however at that time graphene (a 2D layer crystal) are believed thermodynamically too unstable to be produced in real world(Wang & Hu, 2012). After Andre Geim and Konstanstin Novoselov successful production of graphene by scotch tape in 2004 the research attention has been moved forward on graphene strongly(Wang & Hu, 2012).

Figure 1.

Monolayer graphene structure with one atom thickness

There are few ways to produce graphene other than mechanical exfoliation, the common ways are Epitaxial grown, Reduced Graphene Oxide and Chemical Vaporization Deposition (CVD) (J.-L. Chen & Yan, 2010). The main reason to focus on graphene production is its promising electrical property and applications (Liu, Tian, Wang, & Sun, 2011). Intrinsic graphene actually has no band gap, which is unfawerable but we can produce a tune-able band gap of graphene. Firstly is to make it bilayer, then induced E-field to the bilayer or by doping the graphene chemically (M. J. A. Kiani, M T. Rahmani, M. Harun, FK Che, 2013; Mak, Lui, Shan, & Heinz, 2009).

Different layers of graphene indicate different electrical properties. In this part two diverse stacking structures (AA and AB) for bilayer graphene nanoribbons (BGNs) with armchair edge are studied (Barbier, Vasilopoulos, Peeters, & Pereira, 2009). The AA-stacked configuration is metallic, but the AB-stacked which is in our focus behaves like a semiconductor material (with a band gap of 0.02 eV). In the AB structure of bilayer graphene with hexagonal carbon lattice the atoms where located on the top layer of BGNs called A1 and B1, whereas atoms on bottom layer of BGN are A2 and B2as shown in Figure 2 (Fiori & Iannaccone, 2009).

Figure 2.

Schematic of AB bilayer graphene lattice configuration

By applying an exact electric field on BGNs can open a gap on its band energy(Mousavi, Ahmadi, & Sadeghi, 2011; Sadeghi, Ahmadi, Ishak, Mousavi, & Ismail, 2011). In addition, value of band gap energy by applying voltage can be controlled. Theoretical study on BGNs still is a novel and velocity characteristic based on band structure are unexplored yet.

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