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What is Metal Chains

Normal Partitions and Hierarchical Fillings of N-Dimensional Spaces
Cluster compounds that have a skeleton in the form of metal chains, i.e. polymetallic chains formed by metal-metal localized covalent bonds.
Published in Chapter:
Clusters of Chemical Compounds as Polytopes of the Highest Dimension
DOI: 10.4018/978-1-7998-6768-5.ch002
Abstract
General analytical expressions are obtained for calculating the dimension of multi-shell clusters with a common center of shells in those cases when there is a metal atom in the center of the shells and when it is not. The shells can be in the shape of any body of Plato. It has been established that the gamma-copper cluster has the form of a cross-polytope of high dimension. The forms of clusters with ligands of the core of which is a chain of metal atoms or a metal polyhedron are geometrically investigated. It is shown that if the skeleton is a chain of metal atoms, then the cluster is polytope composed of two polytopes of higher dimension adjacent to each other along a flat section containing a chain. If the skeleton is a metal polyhedron, then a cluster of higher dimension has several ligand shells.
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More Results
Closed Metal Cycles in Clusters With Ligands
Cluster compounds that have a skeleton in the form of metal chains, that is, polymetallic chains formed by metal-metal localized covalent bonds.
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Chains of Metallic Clusters With Ligands
Cluster compounds that have a skeleton in the form of metal chains, that is, polymetallic chains formed by metal-metal localized covalent bonds.
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The Polytopes of the Higher Dimension in Physics and Chemistry and Construction of Spaces of the Higher Dimension
Cluster compounds that have a skeleton in the form of metal chains, i.e., polymetallic chains formed by metal-metal localized covalent bonds.
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